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But also, the opposite way is conceivable: if there is a lack of biotin, vitamin B12 cannot fulfil its function in the citrate cycle and remains unused in the tissue – possibly leading to the behavioural change of the skin bacteria already discussed

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71−73 Thus, according to the Jablonski diagram, as shown in Scheme 1, when a molecule absorbs a photon and returns to the singlet excited state, there are three competitive pathways to release the excited-state energy and return to the ground state: (i) radiative decay referred to as fluorescence emission, (ii) intersystem crossing (ISC) transition from the singlet excited state to the lowest triplet state with the further release of energy through phosphorescence or transfer to oxygen to generate ROS, and (iii) nonradiative heat dissipation, which is desirable for photothermal therapy (PTT) and photoacoustic imaging (PAI)